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4hv.org :: Forums :: Chemistry
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Indium zinc oxide?

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Conundrum
Sun May 27 2012, 12:34AM Print
Conundrum Registered Member #96 Joined: Thu Feb 09 2006, 05:37PM
Location: CI, Earth
Posts: 4059
Hi all.
Just found this interesting page.
Link2

Am I right in saying that zinc chloride and indium chloride made by dissolving both metals in HCl then doing the standard hot glass plating technique that works with stannous chloride would generate layers of IZO ?

Link2 describes transistors made from indium galliium zinc oxide (IGZO) that are transparent.

Thanks!
-A
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Wolfram
Sun May 27 2012, 12:59PM
Wolfram Registered Member #33 Joined: Sat Feb 04 2006, 01:31PM
Location: Norway
Posts: 971
The stannous chloride used for making conductive glass can't be made by dissolving tin in aqueous HCl (it needs to be anhydrous), so I don't think this method would work with indium/zinc either.

This Link2 paper has a procedure for depositing IZO films on a silicon dioxide layer on a silicon wafer, it's probably a much better starting point than throwing together random chemicals and wondering why it doesn't work.

Precursor solution for fabricating IZO thin films was prepared by
dissolving 0.1 M of zinc acetate dihydrate
ZnOAc2·2H2O and
0.1 M of indium acetate
InOAc3 in 2-methoxyethanol at 50°C.
ZnOAc2·2H2O has limited solubility in alcohols and its precursor
solution is easily precipitated or gelled. InOAc3 is not soluble in
2-methoxyethanol. Thus, ZnOAc2·2H2O and InOAc3 require
stabilizing agents for dissolution and formation of stable sol.20-23
Diethanolamine DEA
of 0.4 M and acetylacetone acac
of 0.4 M
were used to stabilize the IZO precursor solution.
Heavily boron p

-doped silicon substrate was used in an
inverted-gate structure for the fabrication of IZO-based TTFTs. Silicon
dioxide with a thickness of 120 nm was thermally grown on top
of the silicon substrate and used as gate dielectric. IZO solution was
spin-coated on the SiO2/Si substrates at a speed of 8000 rpm for
30 s and annealed at 500°C for 1 h in a furnace in an atmospheric
environment. An IZO thin film with a thickness of about 10 nm was
obtained on top of the SiO2.
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