Indium zinc oxide?
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Conundrum
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Sun May 27 2012, 12:34AM
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Registered Member #96
Joined: Thu Feb 09 2006, 05:37PM
Location: CI, Earth
Posts: 4062
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Hi all. Just found this interesting page.

Am I right in saying that zinc chloride and indium chloride made by dissolving both metals in HCl then doing the standard hot glass plating technique that works with stannous chloride would generate layers of IZO ?
describes transistors made from indium galliium zinc oxide (IGZO) that are transparent.
Thanks! -A
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Wolfram
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Registered Member #33
Joined: Sat Feb 04 2006, 01:31PM
Location: Norway
Posts: 971
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The stannous chloride used for making conductive glass can't be made by dissolving tin in aqueous HCl (it needs to be anhydrous), so I don't think this method would work with indium/zinc either.
This paper has a procedure for depositing IZO films on a silicon dioxide layer on a silicon wafer, it's probably a much better starting point than throwing together random chemicals and wondering why it doesn't work.
Precursor solution for fabricating IZO thin films was prepared by dissolving 0.1 M of zinc acetate dihydrate ZnOAc2·2H2O and 0.1 M of indium acetate InOAc3 in 2-methoxyethanol at 50°C. ZnOAc2·2H2O has limited solubility in alcohols and its precursor solution is easily precipitated or gelled. InOAc3 is not soluble in 2-methoxyethanol. Thus, ZnOAc2·2H2O and InOAc3 require stabilizing agents for dissolution and formation of stable sol.20-23 Diethanolamine DEA of 0.4 M and acetylacetone acac of 0.4 M were used to stabilize the IZO precursor solution. Heavily boron p
-doped silicon substrate was used in an inverted-gate structure for the fabrication of IZO-based TTFTs. Silicon dioxide with a thickness of 120 nm was thermally grown on top of the silicon substrate and used as gate dielectric. IZO solution was spin-coated on the SiO2/Si substrates at a speed of 8000 rpm for 30 s and annealed at 500°C for 1 h in a furnace in an atmospheric environment. An IZO thin film with a thickness of about 10 nm was obtained on top of the SiO2.
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