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... wrote: "I found the comment that the charge falls to 0 and then reverses to be the most interesting, the time scale of a few weeks seems to rule out any possible explanations "
Thompson's Theorem: When charges move under the action of the field strengh, the energy of the field diminishes by the amount of the work done. The charges will accordingly,so far as they are free to move, arrange themselves in such a way that the field energy will have the least possible value.(Abraham M & Becker R. pp87-the classical theory of electricity and magnetism (1932)
Whatever transitional polarities were, the final one would have to satisfy this theorem.
Observation probably could be done with a simple gold leaf electroscope. Short of gold? In these tough times perhas a piece of metalic Christmas tinsel would do.
I can only imagine the electrets you could make using this gear. The potential difference is >5 million volts! If you substitute the acrylic in the video with PTFE you could manufacture the insulated ball finished and properly sealed and then run it spinning through the accellerator to reduce the radiation strain on the PTFE. Positive monopoles are a little trickier though.
The molten plastic and metal powder idea seems a little more practical though. I would suggest making a rod and then a saw for the monopoles. Can't say I have much experience to rely on, but my common sense tells that to me. Or maybe some themoplastic nylon... Melts at 65 degrees. Much more workable, but as you say durability will be a problem.
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