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Weird phenomenon called metal whiskers

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Dr. Dark Current
Thu Dec 04 2008, 04:16PM Print
Dr. Dark Current Registered Member #152 Joined: Sun Feb 12 2006, 03:36PM
Location: Czech Rep.
Posts: 3384
I just came across this Link2 and found it interesting. The mechanism behind this strange and bizzare phenomenon is not yet understood.

This is what I call a living metal! tongue



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aonomus
Thu Dec 04 2008, 04:25PM
aonomus Registered Member #1497 Joined: Thu May 22 2008, 05:24AM
Location: Toronto, Ontario, Canada
Posts: 801
I remember reading somewhere (can't remember sadly) that the theory at the time was a small hole in the oxide forms, and the metal (tin in that paper) would be squeezed through the hole like toothpaste...

It might explain why sometimes you can take something really old that hasn't been disturbed, move it, have it stop working, clean and dust it out, and have it start working again.
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Proud Mary
Thu Dec 04 2008, 04:43PM
Proud Mary Registered Member #543 Joined: Tue Feb 20 2007, 04:26PM
Location: UK
Posts: 4992
I wonder how the whiskers know what shape they are supposed to be, which direction to grow in, how long they should grow, when their growth should start and stop, and whether they are 'aware' of the presence of other whiskers which might retard their own development.

Does the metal lose mass to the whiskers? If so, what replaces it?

A lot to think about! cheesey

Thank you for a thought-provoking post!

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Wolfram
Thu Dec 04 2008, 04:47PM
Wolfram Registered Member #33 Joined: Sat Feb 04 2006, 01:31PM
Location: Norway
Posts: 971
Fascinating stuff, but very annoying. I have a lot of problems with whisker growth inside my Hammond organ, shorting out switches and busbars. Some of the metal surfaces inside it are visibly hairy.
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Dr. Dark Current
Thu Dec 04 2008, 04:56PM
Dr. Dark Current Registered Member #152 Joined: Sun Feb 12 2006, 03:36PM
Location: Czech Rep.
Posts: 3384
Harry wrote ...

Does the metal lose mass to the whiskers? If so, what replaces it?
Great question! Of course the whiskers have some mass, and it must come from the metal (or not?? suprised)

I guess the only explanation is that the metal becomes hollow under the whisker...


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GeordieBoy
Thu Dec 04 2008, 05:06PM
GeordieBoy Registered Member #1232 Joined: Wed Jan 16 2008, 10:53PM
Location: Doon tha Toon!
Posts: 881
The phenomenon of tin whiskers is quite well known in the electronics industry. Up until recently it has been dealt with by the inclusion of lead into solder, and not using bright tin finish for component leadframes etc. Lead was found highly effective at preventing whisker growth. Then someone had the smart idea of outlawing lead from electronics!

I wonder if there will be a wave of electronic devices failing due to tin whisker growth to hit consumer appliances 10 years from now!

Of course life-support technologies and military applications are exempt from the move to Pb-free. So any application in which you are either trying to sustain life or promptly end it will likely not be effected! angry

Link2

-Richie,
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Proud Mary
Thu Dec 04 2008, 06:12PM
Proud Mary Registered Member #543 Joined: Tue Feb 20 2007, 04:26PM
Location: UK
Posts: 4992
I had a little poke about on Google, and it seems that the whiskers - and how to grow them to order - are an important area of nano-materials research.
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LithiumLord
Thu Dec 04 2008, 06:21PM
LithiumLord Registered Member #1739 Joined: Fri Oct 03 2008, 10:05AM
Location: Moscow, Russia
Posts: 261
sorry guys, just couldn't hold :D
Link2
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Conundrum
Thu Dec 04 2008, 06:26PM
Conundrum Registered Member #96 Joined: Thu Feb 09 2006, 05:37PM
Location: CI, Earth
Posts: 4061
interesting. i did hear something about them even growing through epoxy encapsulant but taking a lot longer.

I'll bet that in a few years they will probably be growing them on demand to use as inter-chip interconnects..
-A
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aonomus
Thu Dec 04 2008, 07:24PM
aonomus Registered Member #1497 Joined: Thu May 22 2008, 05:24AM
Location: Toronto, Ontario, Canada
Posts: 801
Does anyone know if mixing non-ROHS and ROHS compliant materials will hasten whisker formation?
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