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Registered Member #96
Joined: Thu Feb 09 2006, 05:37PM
Location: CI, Earth
Posts: 4061
This is of relevance to me as I am also using Li-Ion cells for my electric bike build. As there are significant safety issues even with the controllers I have, does anyone else have any ideas for adding safety features?
So far it appears that the failed cell(s) did not overcharge, which leaves cell defect at manufacture or some other anomaly. I would theorise that the problem may in fact be with the safety vents on the cells as they are very large format (Liquid) with more in common with a lead acid. If this opened up during flight due to a combination of pressure changes and temperature then didn't reseal, the cell thus affected could have been contaminated with moisture leading to a runaway condition at full charge.
Registered Member #30
Joined: Fri Feb 03 2006, 10:52AM
Location: Glasgow, Scotland
Posts: 6706
Lithium ion batteries will 'splode now and again for no apparent reason. Airlines don't allow them in checked baggage, they keep them in the cabin where the crew can put them out in flight.
Of course the plane's own batteries are magical aerospace grade units that can never catch fire
Registered Member #5258
Joined: Sun Jun 10 2012, 10:15PM
Location: Missouri - USA
Posts: 119
I would not want to be one of the engineers that had any part of that idiocy even if it was just a manufacturing defect.
Andre, If I were using large Li-ion cells on anything I would at minimum monitor temperature of the vents or upper most portion of the cell. And initiate a shutdown/sound an alarm in the event of a high temp alarm. There are other preventive measures that should definitely go into place such as power in/out monitoring, environmental monitoring, etc since the temp alarm might only notify you once irreversible thermal runaway has begun.
Registered Member #162
Joined: Mon Feb 13 2006, 10:25AM
Location: United Kingdom
Posts: 3140
I suspect that the problems may be related to amp.hour capacity vs. temperature, a lithium ion battery can store more energy at room temperature than when cold, so if a battery is fully charged at room temperature, where do the amp.hours go to when the battery is cold?
I have been charging current-limited to 4.2 V for c85% capacity for this reason could charge until charging current drops to x 1/20th of C for full charge but the extra 15% isn't worth the risk, for my applications.
Registered Member #3414
Joined: Sun Nov 14 2010, 05:05PM
Location: UK
Posts: 4245
Sulaiman wrote ...
I suspect that the problems may be related to amp.hour capacity vs. temperature, a lithium ion battery can store more energy at room temperature than when cold, so if a battery is fully charged at room temperature, where do the amp.hours go to when the battery is cold?
I have been charging current-limited to 4.2 V for c85% capacity for this reason could charge until charging current drops to x 1/20th of C for full charge but the extra 15% isn't worth the risk, for my applications.
Severe cold could also have caused the problem with the cracked window, and possibly the leaky pipework as well.
Registered Member #195
Joined: Fri Feb 17 2006, 08:27PM
Location: Berkeley, ca.
Posts: 1111
At work we had a li-ion project and and the cells were packed prety tight. during the testing they ignited in there steal chamber and melted the inside. they evacuated the building and the fire department wouldn't tuch it
Registered Member #96
Joined: Thu Feb 09 2006, 05:37PM
Location: CI, Earth
Posts: 4061
Lol.. Corollary to Murphy's law of Conservation of Flammability. Expense is proportional to the resulting KABLAMMO when it does finally vent with flame.
Registered Member #2463
Joined: Wed Nov 11 2009, 03:49AM
Location:
Posts: 1546
Just looking at the image of the damaged battery module, it is hard to tell what is the fire extinguisher compound and what is the overheated parts. However the battery buss work looks intact as do the terminals. I wonder if that white plastic guard (against some fool dropping a wrench across the terminals) had melted.
The wiring kinda looks like an electric forklift harness I shorted out once .B-)
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