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4hv.org :: Forums :: High Voltage
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electrical arc colors, what causes different colors?

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PresentTeck
Tue Oct 04 2011, 11:20PM Print
PresentTeck Registered Member #3922 Joined: Thu Jun 02 2011, 06:24AM
Location:
Posts: 23
me and my science teacher have been talking about high voltage and atoms and such, specifically why an arc from a MOT will be orange-ish in color and larger, while the higher voltage arcs are blue and small.

we have talked about how it could be heat difference that makes it change, or voltage, but he thinks there has to be something more... like how if you put less energy through a florescent tube it simply glows dimmer.

I looked all over the internet, but nothing i could find told me anything other than adding chemicals to achieve a different color.

Could it just be different levels of excitement in the atoms?

If anyone could point me in the right direction, has a document to show me, or even a simple answer i would greatly appreciate it. :)

PS: in this case we are simply talking about an arc through air.
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Patrick
Wed Oct 05 2011, 12:19AM
Patrick Registered Member #2431 Joined: Tue Oct 13 2009, 09:47PM
Location: Chico, CA. USA
Posts: 5639
What are your electrodes made of?
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PresentTeck
Wed Oct 05 2011, 12:26AM
PresentTeck Registered Member #3922 Joined: Thu Jun 02 2011, 06:24AM
Location:
Posts: 23
they are steel electrodes,

I also notice that it gets more orange and larger the more capacitors i hook up to it in parallel
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Patrick
Wed Oct 05 2011, 12:48AM
Patrick Registered Member #2431 Joined: Tue Oct 13 2009, 09:47PM
Location: Chico, CA. USA
Posts: 5639
Generally, the colors of plasma (or salts burned in air) is related to the elemental identity of the atoms in question. Some of that orange your seeing may be Fe (l,ll,lll) from the steel (as steel is mostly iron).

Are you in high school?
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PresentTeck
Wed Oct 05 2011, 01:01AM
PresentTeck Registered Member #3922 Joined: Thu Jun 02 2011, 06:24AM
Location:
Posts: 23
i thought about that, but would that make the entire arc orange? here's a video of it:


skip to about half way to see it going.

as you can see there is blue near the ends, but the center, especially the furthest from the electrodes is the orangest.
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Patrick
Wed Oct 05 2011, 01:06AM
Patrick Registered Member #2431 Joined: Tue Oct 13 2009, 09:47PM
Location: Chico, CA. USA
Posts: 5639
wELL someone with more chemistry experience may have to explain this further, but remember the ions can be stripped out of solid electrodes, then accellerated buy E-field and thermal forces, so the color could be differ by location throughout the arc.

Im pretty sure this is largely or entirely atomic spectra were seeing here.
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haxor5354
Wed Oct 05 2011, 01:14AM
haxor5354 Registered Member #2063 Joined: Sat Apr 04 2009, 03:16PM
Location: Toronto
Posts: 352
when the atoms/molecules of you electrode is in their excited state, they whould drop back down to its ground state, and a photon would be released during the drop in energy level.

so depending on your electrodes you will have different colors, if you have a light prism with you, you can try a quick experiment. direct the arc's light into the prism and you should see a series of bright lines coming out of the prism, instead of a full spectrum of colors (BTW this is called bright line spectroscopy).


dip your electrodes in salt water then arc to it, you should see bright orange arcs
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Patrick
Wed Oct 05 2011, 01:34AM
Patrick Registered Member #2431 Joined: Tue Oct 13 2009, 09:47PM
Location: Chico, CA. USA
Posts: 5639
the blue may be oxygen/ozone/nitrogen oxides. let me look in my CRC handookor cheistry.
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PresentTeck
Wed Oct 05 2011, 01:46AM
PresentTeck Registered Member #3922 Joined: Thu Jun 02 2011, 06:24AM
Location:
Posts: 23
we have some spectroscopy lenses in my science class, i'll try that sometime.

any idea why the higher voltage burns clean and blue instead of huge and orange?

you can also see the orange color when a high voltage switch is triggered VVV


it looks kinda white, but it's from a distance
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Patrick
Wed Oct 05 2011, 01:57AM
Patrick Registered Member #2431 Joined: Tue Oct 13 2009, 09:47PM
Location: Chico, CA. USA
Posts: 5639
Yeah youre right to question why sparks are white/bule/purple yet arcs are orange and yellow.

i believe the explanation is that atomic nitrogen - oxygen are white blue and easy to excite with lower current, while higher powers (more curretn like arcs) are able to pruduce more energy intensive nitrogen oxide molecular compounds, like a nuclear weapon, which dims 1-10 seconds after detonation due to generation of nitric oxide (which is brown as a vapor) which is then burned off and it brightens again.
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