Graphene and bromine

Conundrum, Fri Oct 12 2018, 08:03AM

Hi all.
I might have found something interesting.

A little while back some researchers invented a way to make graphene a better conductor using bromine gas.
also relevant: Link2

Seems that there might be a way to use a bromine *salt* instead in aqueous solution.
If so then it would be a very efffective way to make this compound and obviously upon removal it would retain its properties.
Wonder if anyone else has tried this?
Re: Graphene and bromine
ShieldExperiments, Tue Oct 23 2018, 06:22PM

Well, it makes sense that doping it with a bromide would make it a better conductor. At the scale of Graphene it seems that the salt would act almost like it is in solution when applied to the Graphene.
Re: Graphene and bromine
Conundrum, Sat Feb 02 2019, 09:50AM

Yup. It appears that any halogen works but bromine is better.
(hint: I have a source but it is - problematical. )
Re: Graphene and bromine
Sulaiman, Sat Feb 02 2019, 11:37AM

Liquid or gaseous bromine is not 'friendly' to work with,
potassium bromide is available via eBay but I doubt there would be any reaction,
potassium bromate is also available and it is a fairly strong oxidiser so may work on its own,
but bromide plus bromate at low pH will release bromine, so may be useful ?
Re: Graphene and bromine
Proud Mary, Wed Feb 06 2019, 11:43PM

Sulaiman wrote ...

Liquid or gaseous bromine is not 'friendly' to work with,
potassium bromide is available via eBay but I doubt there would be any reaction,
potassium bromate is also available and it is a fairly strong oxidiser so may work on its own,
but bromide plus bromate at low pH will release bromine, so may be useful ?


Link2
Re: Graphene and bromine
Conundrum, Fri Aug 30 2019, 05:44AM

Worth a try, thanks.
Incidentally I might have found a way to enable "hyperconductivity", not RTSC but very close. Looks like some very simple chemistry can enable a material that contains no silver yet is more conductive than it in the bulk.
In this case it uses quantum effects to increase conductance, at the cost of making the resulting material brittle.