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4hv.org :: Forums :: Chemistry
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lead test

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radiotech
Tue May 04 2010, 06:49PM Print
radiotech Registered Member #2463 Joined: Wed Nov 11 2009, 03:49AM
Location:
Posts: 1546
Does anyone know the formulation of the rub-and-shake lead test kits. I vaguely remember the old stoichimetry routine but need a quick method to know if lead-free solder was used on a circuit board.

Is there another easy way to test?

The kit costs $5. per test. Rub - shake- , then rub the tip on white paper-if it is pink, then lead is present > .5%
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Bored Chemist
Tue May 04 2010, 07:53PM
Bored Chemist Registered Member #193 Joined: Fri Feb 17 2006, 07:04AM
Location: sheffield
Posts: 1022
Do you have a temperature controlled soldering iron?
Ordinary lead free solder melts at a rather higher temperature than the lead/tin stuff.
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radiotech
Wed May 05 2010, 03:52PM
radiotech Registered Member #2463 Joined: Wed Nov 11 2009, 03:49AM
Location:
Posts: 1546
I do not have a soldering iron with a digital readout of tip temp but have many new irons to try some things with. A servicer with one bench soldering station coiuld easily contaminate a lead free board by using an iron previously used with lead based solders. Which soldering irons actually return a measured value fron the tip to the controller/display ? My Weller station used a Currie point switch in the tip so would cycle around a setpoint .


Using your suggestion, I might try a melt test of a scraping of lead and tin solder in a slowly heated flat crucible to see if the test to see which melts first would work.
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frog
Thu May 06 2010, 08:24AM
frog Registered Member #2400 Joined: Mon Sept 28 2009, 10:04AM
Location: Bundaberg, Australia
Posts: 18
If it is possible to scrap a small sample of the solder off the circuit board you could use the flame test to compare the lead based and non lead based solders.
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radiotech
Fri May 07 2010, 01:01AM
radiotech Registered Member #2463 Joined: Wed Nov 11 2009, 03:49AM
Location:
Posts: 1546
Flame test might work. I could try and make a tin and lead salt solution and dip a glass rod with a fine platinum wire into it. I would have to dig up a bunsen burner or use a propane torch if i can get a pure enough flame with the hot zone. the lead solder has tin in it though.

Tin cries. I wonder if I can make the sample cry.
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Proud Mary
Fri May 07 2010, 01:18AM
Proud Mary Registered Member #543 Joined: Tue Feb 20 2007, 04:26PM
Location: UK
Posts: 4992
Scrub the suspect sample with deionized water, which you save and pour into a test tube.

Add a very small amount of ammonium sulphide and give the tube a good shaking.

The presence of even very small amounts of lead will be confirmed by the formation of a brown precipitate.

Yeah, I know, you haven't got any ammonium sulphide, but at least you know what you would have been able to do, had you happened to have any. smile
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radiotech
Mon May 10 2010, 02:58PM
radiotech Registered Member #2463 Joined: Wed Nov 11 2009, 03:49AM
Location:
Posts: 1546
I do have ammonium sulphate and other dodgy stocks and might have-the ide. the pristine water would need some clean glassware to make. (or perhaps this beast could be refurbished)


1273503501 2463 FT88631 Scan0002
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