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4hv.org :: Forums :: Chemistry
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H3O or H40?

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CM
Fri Feb 09 2007, 05:35PM
CM Banned on April 7, 2007
Registered Member #277 Joined: Fri Mar 03 2006, 10:15AM
Location: Florida
Posts: 157
Stop4:

Thanks, that did the trick, I think.

Looking at Water on the Magnetic Properties & Susceptibilities Chart Link2
water appears to be the most negative measurement on the list, therefore, should I assume that translates to water being the most diamagnetic liquid? Sometimes I tend to oversimplify, so I'm asking. CM
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Dr. Shark
Fri Feb 09 2007, 06:32PM
Dr. Shark Registered Member #75 Joined: Thu Feb 09 2006, 09:30AM
Location: Montana, USA
Posts: 711
I also looked at the list, I spotted only three liquids, being:
Mercury (liquid) Hg -33.4
Nitric acid HNO3 -19.9
Water H20 -7.2×10-7 emu
The units on water are different (emu instead of cgs units, whatever that is), so it is impossible to compare - at least for me.

What is your application for this stuff? I am asking because maybe a fine metal power could be substituted for the liquid, which would make things much easier.


PS: some more data on liquids:
Compound Name (−106 ×SI Units:Dimensionless)

Acetone 5.78
Benzene 7.68
Carbon tetrachloride 8.68
Dimethyl sulfoxide 8.55
D2O 8.82
Ethanol 7.23
Ethylene glycol 8.77
D-Glucose (25â—¦C) 10.92
Glycerol 9.79
H2O 9.04
Mannitol 11.40
Methanol 6.66
Myristic acid (60â—¦C) 8.31
Oleic acid (18â—¦C) 8.31
Palmitic acid (62â—¦C) 8.31
Toluene 7.76

from Weast RC. CRC Handbook of Chemistry and
Physics. Boca Raton, FL: CRC Press; 1983.
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stop4stuff
Fri Feb 09 2007, 08:47PM
stop4stuff Registered Member #64 Joined: Thu Feb 09 2006, 06:25AM
Location: Southampton, UK
Posts: 68
from Link2
"emu/cm3 or emu/cc
a CGS unit of magnetization"


the column heading of the Reade chart Link2 says x10-6 & water is shown as x10-7
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CM
Fri Feb 09 2007, 09:25PM
CM Banned on April 7, 2007
Registered Member #277 Joined: Fri Mar 03 2006, 10:15AM
Location: Florida
Posts: 157
I wondered what EMU meant also in the H20 measurement. My application is a variation on this demonstration Link2 but I would prefer to speed things up by using a liquid that is more diamagnetic than water... if it exists and doesn't require exotic conditions to exist as a liquid. CM
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Bored Chemist
Sat Feb 10 2007, 02:25PM
Bored Chemist Registered Member #193 Joined: Fri Feb 17 2006, 07:04AM
Location: sheffield
Posts: 1022
Electromagnetic units rather than centimetre gram second units. Ugh!
Anyway, if what you want to achive is a demonstration of liquid drops repeled by a magnet, cheat.
A helium balloon in air is aparently repeled by the earth's gravitational field. Clearly that's not because it has negative mass, but because the air has a bigger positive mass. In the same way a drop of slightly diamagnetic oil in a strong solution of a paramagnetic salt like MnCl2 would be repelled quite strongly. Paramagnetic effects are typically a hundred times bigger than diamagnetic ones so, even allowing for the fact that the solution isn't pure paramagnetic MnCl2 the overall effect should be bigger. Of course, you could look for materials which are soluble in oil and paramagnetic then use a solution of that with pure water - the water would be repelled and the paramagnetic solution attracted. It's a lot easier to find MnCl2 than, for example, Ferric acetylacetonate.
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