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4hv.org :: Forums :: Chemistry
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Zink Carbon battery failure.

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radiotech
Sat Oct 15 2011, 08:37PM Print
radiotech Registered Member #2463 Joined: Wed Nov 11 2009, 03:49AM
Location:
Posts: 1546
We had a set of 20 6 volt lantern batteries for class use that were bought about 6
years ago, 2 or 3 are bad now, but never were used.

In the past these batteries were tar filled and difficult to take apart , save pulling out
carbon rods, So I decided to open one. They were not tarred in, and the assembly just
popped open at the top.

Two of the four cells had eaten most of the zinc. The two others were pristine, and for
a battery cell with an expiry date in 2008, delivered 6 amps short.

What could of been the starter of the failure of the other two ? There was no liquid anywhere
in the case.

The case is interesting because something else could be built in it, and the assembly
put back into a lantern flashlight. Perhaps change the bulb to LED and change the device
into a combination flashlight/light band transceiver.





1318710911 2463 FT0 Lanternbatt
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klugesmith
Tue Oct 18 2011, 06:44PM
klugesmith Registered Member #2099 Joined: Wed Apr 29 2009, 12:22AM
Location: Los Altos, California
Posts: 1714
Maybe one pair of cells was "shorted" by an internal leakage path between sloppy connections.
It would take about 100 microamps to exhaust them in 6 years.

In what physical positions, within the series string, were the bad cells?
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radiotech
Wed Oct 19 2011, 05:58AM
radiotech Registered Member #2463 Joined: Wed Nov 11 2009, 03:49AM
Location:
Posts: 1546
The corroded ones were is series with the pair that were good. Case wise this made them adjacent.

There was no internal wiring short.
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