Welcome
Username or Email:

Password:


Missing Code




[ ]
[ ]
Online
  • Guests: 22
  • Members: 0
  • Newest Member: omjtest
  • Most ever online: 396
    Guests: 396, Members: 0 on 12 Jan : 12:51
Members Birthdays:
All today's birthdays', congrats!
Linas (34)
Toasty (29)


Next birthdays
05/15 Linas (34)
05/15 Toasty (29)
05/16 kg7bz (68)
Contact
If you need assistance, please send an email to forum at 4hv dot org. To ensure your email is not marked as spam, please include the phrase "4hv help" in the subject line. You can also find assistance via IRC, at irc.shadowworld.net, room #hvcomm.
Support 4hv.org!
Donate:
4hv.org is hosted on a dedicated server. Unfortunately, this server costs and we rely on the help of site members to keep 4hv.org running. Please consider donating. We will place your name on the thanks list and you'll be helping to keep 4hv.org alive and free for everyone. Members whose names appear in red bold have donated recently. Green bold denotes those who have recently donated to keep the server carbon neutral.


Special Thanks To:
  • Aaron Holmes
  • Aaron Wheeler
  • Adam Horden
  • Alan Scrimgeour
  • Andre
  • Andrew Haynes
  • Anonymous000
  • asabase
  • Austin Weil
  • barney
  • Barry
  • Bert Hickman
  • Bill Kukowski
  • Blitzorn
  • Brandon Paradelas
  • Bruce Bowling
  • BubeeMike
  • Byong Park
  • Cesiumsponge
  • Chris F.
  • Chris Hooper
  • Corey Worthington
  • Derek Woodroffe
  • Dalus
  • Dan Strother
  • Daniel Davis
  • Daniel Uhrenholt
  • datasheetarchive
  • Dave Billington
  • Dave Marshall
  • David F.
  • Dennis Rogers
  • drelectrix
  • Dr. John Gudenas
  • Dr. Spark
  • E.TexasTesla
  • eastvoltresearch
  • Eirik Taylor
  • Erik Dyakov
  • Erlend^SE
  • Finn Hammer
  • Firebug24k
  • GalliumMan
  • Gary Peterson
  • George Slade
  • GhostNull
  • Gordon Mcknight
  • Graham Armitage
  • Grant
  • GreySoul
  • Henry H
  • IamSmooth
  • In memory of Leo Powning
  • Jacob Cash
  • James Howells
  • James Pawson
  • Jeff Greenfield
  • Jeff Thomas
  • Jesse Frost
  • Jim Mitchell
  • jlr134
  • Joe Mastroianni
  • John Forcina
  • John Oberg
  • John Willcutt
  • Jon Newcomb
  • klugesmith
  • Leslie Wright
  • Lutz Hoffman
  • Mads Barnkob
  • Martin King
  • Mats Karlsson
  • Matt Gibson
  • Matthew Guidry
  • mbd
  • Michael D'Angelo
  • Mikkel
  • mileswaldron
  • mister_rf
  • Neil Foster
  • Nick de Smith
  • Nick Soroka
  • nicklenorp
  • Nik
  • Norman Stanley
  • Patrick Coleman
  • Paul Brodie
  • Paul Jordan
  • Paul Montgomery
  • Ped
  • Peter Krogen
  • Peter Terren
  • PhilGood
  • Richard Feldman
  • Robert Bush
  • Royce Bailey
  • Scott Fusare
  • Scott Newman
  • smiffy
  • Stella
  • Steven Busic
  • Steve Conner
  • Steve Jones
  • Steve Ward
  • Sulaiman
  • Thomas Coyle
  • Thomas A. Wallace
  • Thomas W
  • Timo
  • Torch
  • Ulf Jonsson
  • vasil
  • Vaxian
  • vladi mazzilli
  • wastehl
  • Weston
  • William Kim
  • William N.
  • William Stehl
  • Wesley Venis
The aforementioned have contributed financially to the continuing triumph of 4hv.org. They are deserving of my most heartfelt thanks.
Forums
4hv.org :: Forums :: Chemistry
« Previous topic | Next topic »   

Printing with Polymorph

1 2 
Move Thread LAN_403
Conundrum
Tue May 31 2011, 05:34PM Print
Conundrum Registered Member #96 Joined: Thu Feb 09 2006, 05:37PM
Location: CI, Earth
Posts: 4059
Hi all.

Seems that mixing Polymorph (aka Polycaprolactone) with acetone and then printing the resulting mixture with a one nozzle print head made of a pair of opposed piezo disk speakers and Epoxy casing could allow a really really cheap 3-D prototyping machine to be built.

Turns out that people have been aware of this for a while but no-one knew how to make it "print" easily.
The DIY print head is the required secret sauce.

No this won't work with an Epson (tm) head, the acetone will turn it into foul smelling goo with wires sticking out.

Comments?

-A

"Bother!" said Pooh, as his 32GB microSD turned out to be a fake...
Back to top
Pinky's Brain
Sun Jun 05 2011, 06:30AM
Pinky's Brain Registered Member #2901 Joined: Thu Jun 03 2010, 01:25PM
Location:
Posts: 837
How would you get it to solidify correctly and fast enough?
Back to top
Conundrum
Mon Jun 06 2011, 07:59AM
Conundrum Registered Member #96 Joined: Thu Feb 09 2006, 05:37PM
Location: CI, Earth
Posts: 4059
Applied heat would do it, my suggestion is to use a modified Mendel which moves the workpiece rather than the print head.

Ought to work, once the solvent has evaporated which (I tried it) takes about five seconds with the mixture I used of 75g acetone 15g polymorph and 0.5g strontium aluminate it sets just like normal Polymorph.

To make it requires a hot water bath to encourage full mixture of the components, or if you are a mad scientist like me 10 seconds in the microwave smile
*DO NOT* do this, use a water bath, kthx.

I used a surplus glass bottle which originally contained an acetone-alcohol mixture so the lid should be able to last.

It occurs to me that the technique should also work with other chemicals such as iron particles for making DIY inductors, or EL phosphor for making flexible EL sheet without the usual hassles.
I expect that coating the plastic with ITO then a protective flexible layer should work.

Did you know that a broken LiFePO4 battery has about 4 feet of copper sheet inside suitable for such experiments? I sure didn't.

Wonder if I could sell this for coating fishing floats or something? I'd used conventional Polymorph mixed by hand with aluminate but this stuff seems far superior and potentially easier to coat onto any compatible surface.

-A
Back to top
Pinky's Brain
Mon Jun 06 2011, 09:42AM
Pinky's Brain Registered Member #2901 Joined: Thu Jun 03 2010, 01:25PM
Location:
Posts: 837
I don't see how the droplet would maintain shape during hardening. With the normal application the heated plastic stays together out of sheer viscosity, yours would just splatter all over the work piece AFAICS.
Back to top
Conundrum
Mon Jun 06 2011, 01:47PM
Conundrum Registered Member #96 Joined: Thu Feb 09 2006, 05:37PM
Location: CI, Earth
Posts: 4059
Will have to try it and get back to you.

From the looks of it a gradient heated print head may get around this, as the solvent would flash boil during extrusion.
I may need to use a Peltier somewhere to keep the rest of the plastic at its liquidus temperature.

-A
Back to top
Shrad
Tue Jun 07 2011, 01:56PM
Shrad Registered Member #3215 Joined: Sun Sept 19 2010, 08:42PM
Location:
Posts: 780
you could use a laser diode focused to the needle point and send a quick light pulse to cure it

but will it cure with 405nm? the main advantage is the focal point you could achieve, less than 100µm is easy
Back to top
Pinky's Brain
Tue Jun 07 2011, 05:49PM
Pinky's Brain Registered Member #2901 Joined: Thu Jun 03 2010, 01:25PM
Location:
Posts: 837
These guys get OMFG good resolution with inkjet in 3D ...
Link2
Link2

If you put down support and white material first as a sort of mold you could use a low viscosity transparent UV resin together with a colour inkjet printer to create full colour objects (the low viscosity resin would go in between the support and the white material, and mix with with ink before curing).
Back to top
Conundrum
Tue Jun 07 2011, 11:14PM
Conundrum Registered Member #96 Joined: Thu Feb 09 2006, 05:37PM
Location: CI, Earth
Posts: 4059
Interesting.

I had the intriguing idea of using microcrystals of silicon carbide distributed through a somewhat conductive matrix to make primitive semiconductors, using a high voltage to align the crystals during curing.

Sound possible?
the same method has been used to "burn out" carbon nanotubes which are conductive rather than semiconductive so that the properties can be controlled.

-A
Back to top
Pinky's Brain
Wed Jun 08 2011, 01:00PM
Pinky's Brain Registered Member #2901 Joined: Thu Jun 03 2010, 01:25PM
Location:
Posts: 837
I think it would be extremely leaky ...

To get back to DIY inkjet printheads ... how about simply doing a HV discharge in the inkchannel?
Back to top
Conundrum
Wed Jun 08 2011, 06:43PM
Conundrum Registered Member #96 Joined: Thu Feb 09 2006, 05:37PM
Location: CI, Earth
Posts: 4059
Yep that ought to work.

Wonder if EPE would publish this as an article if I get repeatable results?
-A
Back to top
1 2 

Moderator(s): Chris Russell, Noelle, Alex, Tesladownunder, Dave Marshall, Dave Billington, Bjørn, Steve Conner, Wolfram, Kizmo, Mads Barnkob

Go to:

Powered by e107 Forum System
 
Legal Information
This site is powered by e107, which is released under the GNU GPL License. All work on this site, except where otherwise noted, is licensed under a Creative Commons Attribution-ShareAlike 2.5 License. By submitting any information to this site, you agree that anything submitted will be so licensed. Please read our Disclaimer and Policies page for information on your rights and responsibilities regarding this site.